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Which of the following statements is true concerning redox reactions?

  1. Only oxidation occurs without reduction.

  2. Only reduction occurs without oxidation.

  3. Oxidation and reduction can occur independently.

  4. Oxidation and reduction always occur together.

The correct answer is: Oxidation and reduction always occur together.

In redox reactions, oxidation and reduction are intrinsically linked processes that cannot occur in isolation; wherever there is oxidation, there must also be a corresponding reduction, and vice versa. This is because oxidation involves the loss of electrons, while reduction involves the gain of electrons. When a substance oxidizes, it donates electrons to another substance, which then reduces by accepting those electrons. The simultaneous occurrence of these processes ensures the conservation of charge and mass in the reaction. Therefore, it is impossible to have a scenario where only oxidation occurs without reduction or only reduction without oxidation, making the statement that they always occur together a fundamental principle of redox chemistry. This understanding is critical in various applications, including electrochemistry, metabolism, and many industrial processes, where the interplay of electron transfer drives chemical transformations.